Article Content
Highlights
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Relaxation dynamics of the Blume-Capel model with a random crystal are analyzed.
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Irreversible thermodynamics theory is utilized.
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A partially ordered phase emerges when disorder amplitude passes a threshold.
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The effect of randomness on multicritical relaxation is studied.
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Crystal field dependence of the relaxation time is represented.
Abstract
The present study employs statistical equilibrium theory and irreversible thermodynamics to examine the relaxation dynamics of a spin-1 Blume-Capel model with a quenched random crystal field. First, the investigation focuses on the variation of the dipolar and quadrupolar order parameters as a function of the temperature and the crystal field within the mean-field approximation. It has been established that the mean-field equilibrium behavior of the model is characterized by phase diagrams exhibiting three distinct structures for varying values of the random fluctuation strength of the crystal field () in the temperature versus crystal field plane. The induced novel phase resulting from disorders and the subsequent first-order phase transition at higher temperatures are highlighted through the dependence of the magnetization and quadrupole moment on the crystal field. It is assumed that the system has departed from equilibrium due to a small external magnetic field, a generalized force, and a current, all defined based on the production of magnetic Gibbs free energy, to formulate the relaxation behavior. The linearized kinetic equation was derived to determine the characteristic relaxation time. The relaxation time is demonstrated as a function of temperature and the crystal field for varying values of . The present study investigates the thermal and crystal field dependencies of relaxation times near critical, ordered critical, multicritical points, and first-order transitions. The characteristic relaxation time increases exponentially near the critical, tricritical, and isolated critical points, approaching an infinite duration.
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Introduction
The multicritical behaviors and thermodynamic properties of disordered magnetic systems have been a focus of investigations in condensed-matter physics because their properties are richer and more complex than those of their pure and non-disordered counterparts [[1], [2], [3], [4], [5]]. In particular, the magnetic properties of these systems have been examined in the presence of random single-ion anisotropies [6,7], random magnetic fields [8,9], and disorders in the couplings between spins [10,11]. The impact of random field effects on magnetic systems has been the subject of experimental investigations [12]. A random crystal field was introduced to observe the critical behavior of 3He-4He mixtures in aerogel, which was modeled using the spin-1 Blume-Capel (BC) system. In this model, the crystal fields are assumed to have positive or negative values. The positive crystal field is defined as a bulk field that controls the concentration of 3He atoms. The negative crystal field is correspondingly defined as the field at the pore-grain interface [13,14]. The development of a superfluid 3He-4He solution has also been achieved through experimental studies [15,16].
As demonstrated in the relevant literature, the equilibrium properties of the BC model have been the subject of study in the presence of a random crystal field by various authors [[17], [18], [19], [20], [21]]. Recent studies have revealed new phase diagrams, which include a partially ferromagnetic phase. The experimental interest in this model has arisen from its potential to describe cooperative physical systems, including, but not limited to, superconducting films [22], dysprosium aluminum garnet [23], liquid crystals [24], metallic alloys [25], magnetic thin films [26], and others. The BC model has been extensively investigated in theoretical studies by a variety of methods, including mean-field theory (MFT) [17,18,[27], [28], [29]], renormalization group calculations (RGT) [6,14,30,31], Monte Carlo simulations [[32], [33], [34], [35]], effective field theory [36], the cluster variation approach [37], the replica method [5], and the pair approximation approach [38]. Randomness significantly affects the behaviors above, as shown in the example; the phase diagrams present rich behavior in these studies under quenched randomness. Quenched randomness can cause changes to the critical behavior of a system. For instance, it has been shown to cause first-order transitions to be replaced by continuous transitions in two dimensions and to lower the tricritical temperature in higher dimensions [7,8,39,40]. The equilibrium phase diagrams of the spin-1 BC model under a bimodal crystal field have been investigated using the mean-field approximation (MFA) by Bocarra et al. [17], the RGT by Branco et al. [14], and El Bouziani et al. [31]. The equilibrium behavior of the mean-field spin-1 Blume-Capel model with another form of random crystal-field distributions corresponding to quenched diluted single-ion anisotropy has been studied extensively by Benyoussef et al. [6]. Moreover, studies on dynamic phase diagrams [41,42] and the application of relaxation theory to various systems [43,44] have drawn significant attention to this model [43,44]. The behavior of the relaxation time () and the dynamics of the system in the neighborhood of phase transitions have been the subject of experimental research for quite a considerable time [45,46]. To the best of our knowledge, the relaxation dynamics of the spin-1 BC model with quenched random crystal field distributed according to a symmetric, two-valued probability distribution defined by two delta functions have not yet been studied. Our main goal in the present work is to investigate the effect of quenched disorder on the relaxation processes that occur under the application of a small field for quite a short time. To this end, the kinetic equation for the magnetization () is derived within the framework of linear response theory. Subsequently, the temperature () and the crystal field () dependencies of the relaxation time in the neighborhood of the phase-transition points are obtained by solving the kinetic equation for the magnetization. The focal point of this study is the behavior of the relaxation time, which characterizes the magnetization relaxation process in proximity to the critical, isolated critical, multicritical, and first-order transition points. The findings presented here constitute a novel contribution to the field, owing to the observation of successive first-order phase transitions, which occur only under strong disorder.
The structure of this work is delineated as follows: Section 2 provides a concise exposition of the model and details its equilibrium properties under the MFA. The third section offers a detailed exposition of the derivation of the kinetic equation and the relaxation time. Section 4 provides the results of the present study, focusing on the MFA phase diagrams and relaxation behavior of the system in the vicinity of critical, multicritical, and first-order points. Finally, the last section provides a summary and conclusion.
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Section snippets
Spin-1 Blume-Capel model with random crystal field
The Hamiltonian of the spin-1 BC model with a quenched random crystal field is typically expressed as [1,17,[41], [42], [43]]where . is the spin variable (at site ) that takes on three values . In the first term in (1), indicates the summation over the nearest-neighbor spins at sites and and describes the ferromagnetic (FM) (bilinear) exchange coupling between nearest-neighbor spins, while the second term describes a random crystal field distributed
Derivations of the kinetic equation and relaxation time
For the derivations of the kinetic equation and relaxation time, we first have to calculate the magnetic Gibbs energy function via the Legendre transformation. Letting , and be the configuration of the internal energy, entropy, external magnetic field, and number of spins, respectively, the magnetic Gibbs energy function is defined as [43]. The reduced MFA Gibbs free energy per spin can be written as:
Results and discussion
In this section, we present the phase diagram for , , and , along with the critical and multicritical behaviors of the relaxation phenomena. To achieve this, Eqs. (5) and (10) are solved numerically, and the solution that minimizes the free energy given in Eq. (4) is selected. Subsequently, the equations of state are solved in the absence of an external magnetic field (). The temperature and crystal field dependence of the single relaxation time () is obtained. In
Summary and conclusion
In the present work, the effect of quenched disorder on the relaxation dynamics of the BC model, where the local crystal field, conjugate to the spins, is random with a bimodal distribution, has been investigated. The partition function has been averaged out in the quenched system, with the free energy being the primary focus [55]. This study focuses on the final stage of the approach to equilibrium, which is the stage at which the MFA global phase diagrams are obtained. The regular spin-1
CRediT authorship contribution statement
Songül Özüm: Writing – review & editing, Writing – original draft, Visualization, Validation, Supervision, Conceptualization. Elif Sünnetci: Visualization. Gül Gülpınar: Validation, Supervision, Methodology, Conceptualization. Rıza Erdem: Writing – review & editing, Validation, Supervision, Conceptualization.
Declaration of competing ınterest
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
The author is an Editorial Board Member/Editor-in-Chief/Associate Editor/Guest Editor for this journal and was not involved in the editorial review or the decision to publish this article.
Acknowledgments
The authors are grateful to the Scientific and Technological Research Council of Turkey (TÜBİTAK 2209-A, Contract No. 1919B012204755) for the financial support of this study.
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