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Abstract

ZnO and ZnO/graphene nanoplatelet (GNP) nanocomposite samples were prepared via a facile hydrothermal method in this study. The crystal structure of both samples was evaluated and confirmed, and their lattice parameters were estimated. The morphology of ZnO revealed separated nanoparticles, while the ZnO nanoparticles were present between graphene layers in the ZnO/graphene nanoplatelet composite. Analytical observation indicated that both samples are pure synthesized material with no elemental impurities. Subsequently, they were evaluated as a conductometric sensor for the detection of N,N-dimethylformamide (DMF) vapor. The ZnO/graphene nanocomposite-based sensor exhibited an impressive response, ranging from 31.34 to 76.60 for DMF concentrations of 30–100 ppm, compared to the ZnO-based sensor at the optimal working temperature of 270°C. The superior sensing performance of the ZnO/graphene sensor is primarily ascribed to the formation of pn heterojunctions within the nanocomposite structure. Its detection limit, estimated at around 72 ppb, underscores its promise as a viable and effective sensing platform.

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References

  1. I.S. Saggu, S. Singh, S. Singh, and S. Sharma, Improved N,N-Dimethylformamide vapor sensing using WSe2/MWCNTs composite at room-temperature. Surf. Interfaces 42, 103403 (2023).

    CAS Google Scholar

  2. N. Dogra and S. Sharma, Selective room-temperature dimethylformamide vapor sensing using MoSe2-rGO composite synthesized via facile hydrothermal method. Mater. Today Commun. 35, 106106 (2023).

    CAS Google Scholar

  3. Q. Chen, J. Li, W. Fu, Y. Yang, W. Zhu, and J. Zhang, Detection of N,N-dimethylformamide vapor down to ppb level using electrospun InYbO nanofibers field-effect transistor. Sens. Actuators B 323, 128676 (2020).

    CAS Google Scholar

  4. W.C. Cooper, A. Chilukoorie, S. Polam, D. Scott, and F. Wiseman, A comparative study on the hydrolysis of acetic anhydride and N,N-dimethylformamide: kinetic isotope effect, transition-state structure, polarity, and solvent effect. J. Phys. Org. Chem. 30, e3701 (2017).

    Google Scholar

  5. N. Sun and B. Yan, Fluorescence detection of urinary N-methylformamide for biomonitoring of human occupational exposure to N,N-dimethylformamide by Eu(III) functionalized MOFs. Sens. Actuators B 261, 153 (2018).

    CAS Google Scholar

  6. T. Wang, Y. Guo, P. Wan, X. Sun, H. Zhang, Z. Yu, and X. Chen, A flexible transparent colorimetric wrist strap sensor. Nanoscale 9, 869 (2017).

    CAS PubMed Google Scholar

  7. T. Wang, L. Zhu, Y. Yue, M.R. Asghari, B. Hosseinzadeh Samani, T. Yamamoto, Y. Mukai, and H. Kanda, N,N-dimethylformamide detection and refractive index sensing using an electrospun polymer/Ti3C2 MXene-TiO2 modified optical fiber sensor. Sens. Actuators, B 417, 136143 (2024).

    CAS Google Scholar

  8. X.L. Xu, M.Y. Wang, G.R. Sun, W. Ma, Z.H. Jin, and S.Y. Ma, Multi-stage hierarchical self-assembled ZnIn2S4/ZnO flexible room temperature sensor for DMF sensing. Vacuum 230, 113709 (2024).

    CAS Google Scholar

  9. X. Wang, Q. Ma, Q. Zhang, Y. Wang, L. Li, D. Zhao, and Z. Liu, Porous double-channel α-Fe2O3/SnO2 heterostructures with multiple electronic transmission routes for the enhanced N,N-dimethylformamide gas-sensing performance. Physica E 155, 115835 (2024).

    CAS Google Scholar

  10. L. Li, J. Li, W. Fo, Y. Lei, S. Wen, Q. Yang, and J. Zhang, Highly sensitive and selective low-cost SnZrO nanofiber field-effect transistor for N,N-dimethylformamide vapour detection at room temperature. Sens. Actuators B 367, 132155 (2022).

    CAS Google Scholar

  11. F.M. Davoodi, S.M. Rozati, and S. Soltani, Synthesis and characterization of ZnO and Au/ZnO thin films for ethanol gas sensing application. Appl. Phys. A 130, 866 (2024).

    CAS Google Scholar

  12. S. Nejatinia, S. Khadem Charvadeh, and A. Bagheri Khatibani, The effect of graphene and cobalt on ethanol sensing performance of ZnO based sensor prepared by sol–gel method. Jpn. J. Appl. Phys. 61, 017001 (2022).

    CAS Google Scholar

  13. H. Zhang, W.G. Chen, Y.Q. Li, and Z.H. Song, Gas sensing performances of ZnO hierarchical structures for detecting dissolved gases in transformer oil: a mini review. Front. Chem. 6, 508 (2018).

    CAS PubMed PubMed Central Google Scholar

  14. R.T. Ngaloy, A.M. Fontanilla, M.S.R. Soriano, C.S. Pascua, Y. Matsushita, and I.J.A. Agulo, Highly efficient photocatalysis by zinc oxide-reduced graphene oxide (ZnO-rGO) composite synthesized via one-pot room-temperature chemical deposition method. J. Nanotechnol. 2019, 1895043 (2019).

    Google Scholar

  15. S. Saadat Niavol, A. Bagheri Khatibani, H. Milani Moghaddam, and G. Gao, ZnO quantum dots decorated on graphene oxide and graphene nanoplatelets: comparison the structure and sensing properties. Inorg. Chem. Commun. 160, 111957 (2024).

    Google Scholar

  16. Z. Rafiee, A. Mosahebfard, and M.H. Sheikhi, High-performance ZnO nanowires-based glucose biosensor modified by graphene nanoplates. Mater. Sci. Semicond. Process. 115, 105116 (2020).

    CAS Google Scholar

  17. C.F. Kuan, C.L. Chiang, S.H. Lin, W.G. Huang, W.Y. Hsieh, and M.Y. Shen, Characterization and properties of graphene nanoplatelets/XNBR nanocomposites. Polym. Polym. Compos. 26, 59 (2018).

    CAS Google Scholar

  18. H. Porwal and R. Saggar, Comprehensive composite materials II (6.6. Ceramic Matrix Nanocomposites). Ref. Module Mater. Sci. Mater. Eng. 6, 138 (2018).

    CAS Google Scholar

  19. S. Saadat Niavol, H. Milani Moghaddam, A. Bagheri Khatibani, S.F. Hashemi Karouei, F. Hermerschmidt, G. Ligorio, and E.J.W. List Kratochvil, Enhancing both methylene blue photocatalytic degradation and ethanol sensing performances of ZnO/rGO nanocomposite through the variation of GO amount. Appl. Phys. A 128, 733 (2022).

    CAS Google Scholar

  20. J. Du, J. Wu, R. Zhao, H. Yao, T. Asefa, and J. Li, Synthesis and gas-sensing performance of column-shaped zinc oxide doped with-graphene. Mater. Today Proc. 3, 345 (2016).

    Google Scholar

  21. S. Saadat Niavol, A. Bagheri Khatibani, S. Imani, and H. Milani Moghaddam, Ethylene glycol-sensing properties of hydrothermally grown feather-like ZnO nanopowder with abundant oxygen vacancies. J. Mater. Res. 38, 1211 (2023).

    CAS Google Scholar

  22. A.R. Khoshhal, A. Bagheri Khatibani, Z. Tirehdast, M. Shaddoust, and M. Nirouei, Evaluation of experimental and simulated gamma ray shielding ability of ZnCo2O4 and ZnCo2O4/graphene nanoparticles. Opt. Mater. 156, 115953 (2024).

    CAS Google Scholar

  23. A. Bagheri Khatibani and A. Shabankhah, Fabrication and ethanol sensing of sol–gel grown zinc oxide powder: the effect of cobalt and copper doping. Appl. Phys. A 127(5), 308 (2021).

    CAS Google Scholar

  24. S.F. Hashemi Karouei and H. Milani Moghaddam, Effect of surface modification on photocatalytic activity of self-assembled LaFeO3 microspheres. J. Mater. Sci. Mater. Electron. 30, 9334 (2019).

    CAS Google Scholar

  25. H. Beigli, M. Shaddoust, M.H. Ahmadi, and A. Bagheri Khatibani, Effect of low and relatively long-term gamma irradiation on physical properties of ZnO and ZnO: Co thin films. J. Sol Gel Sci. Technol. 108, 798 (2023).

    CAS Google Scholar

  26. S. López-Romero and M. García-H, Photoluminescence and structural properties of ZnO nanorods growth by assisted-hydrothermal method. World J. Condens. Matter Phys. 3, 152 (2013).

    Google Scholar

  27. J. Qin, X. Zhang, C. Yang, M. Cao, M. Ma, and R. Liu, ZnO microspheres- reduced graphene oxide nanocomposite for photocatalytic degradation of methylene blue dye. Appl. Surf. Sci. 392, 196 (2017).

    CAS Google Scholar

  28. A. Bagheri Khatibani, S.M. Rozati, and Z. Bargbidi, Preparation, study and nanoscale growth of indium oxide thin films. Acta Phys. Pol. A 122(1), 220 (2012).

    Google Scholar

  29. S. Singh and S. Sharma, Temperature dependent selective detection of ethanol and methanol using MoS2/TiO2 composite. Sens. Actuators B Chem. 350, 130798 (2022).

    CAS Google Scholar

  30. A. Bagheri Khatibani, M. Abbasi, and S.M. Rozati, Peculiarities of deposition times on gas sensing behaviour of vanadium oxide thin films. Acta Phys. Pol. A 129(6), 1245 (2016).

    Google Scholar

  31. A. Bagheri Khatibani and M. Abbasi, Comparison of gas sensing properties of spray pyrolysed VOx thin films. J. Mater. Sci. Mater. Electron. 26, 5052 (2015).

    CAS Google Scholar

  32. S. Saadat Niavol, A. Bagheri Khatibani, S.F. Hashemi Karouei, S.A. Hejazi Juybari, and H. Milani Moghaddam, Mesoporous Zn2SnO4 for efficient sensing of ethylene glycol vapor. Mater. Chem. Phys. 303, 127799 (2023).

    Google Scholar

  33. V.S. Choudhary, R. Singh, A. Kumar, C.S. Yadav, S. Sharma, J. Garcia, and S.K. Sharma, MoSe2-based room temperature gas sensor with a sub-parts-per-billion limit for ammonia and N,N-dimethylformamide. Mater. Adv. 6(9), 2854 (2025).

    CAS Google Scholar

  34. S. Singh, J. Deb, S. Kumar, U. Sarkar, and S. Sharma, Selective N,N-dimethylformamide vapor sensing using MoSe2/multiwalled carbon nanotube composites at room temperature. ACS Appl. Nano Mater. 5(3), 3913 (2022).

    CAS Google Scholar

  35. S. Singh, I. Singh Saggu, S. Singh, N. Kumar, K. Chen, Z. Xuan, R. Gupta, M.T. Swihart, and S. Sharma, Detection of DMF and NH3 at room temperature using a sensor based on a MoS2/single-walled carbon nanotube composite. ACS Appl. Nano Mater. 6(12), 10698 (2023).

    CAS Google Scholar

  36. A. Sumayli, R.M. Almotawa, and J. Abdullah Alamoudi, Development of a high performance ethylene glycol gas sensor using cobalt doped porous ZnFe2O4 nanostructures. Sci. Rep. 15, 16876 (2025).

    CAS PubMed PubMed Central Google Scholar

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Bagheri Khatibani, A., Saadat Niavol, S., Rasouli Jamnani, S. et al. Fabulous sensing of N,N-Dimethylformamide (DMF) Vapor Using Hydrothermally Prepared Zinc Oxide/Graphene Nanoplatelets Nanocomposite. J. Electron. Mater. (2025). https://doi.org/10.1007/s11664-025-12124-x

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Keywords

  • Zinc oxide
  • graphene nanoplatelets
  • gas sensor
  • DMF vapor
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